Formula and also structure: The chemistry formula the zinc sulfide is ZnS, and its molar massive is 97.47 g/mol. The chemical framework of ZnS is an easy and consists of the zinc metal attached to a sulfur atom through a polar covalent bond.

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Solid zinc sulfide is uncovered in two different crystal forms, alpha (wurtzite) and also beta (sphalerite), which have actually hexagonal and cubic structures, respectively. The beta crystalline (sphalerite) is the more stable type of ZnS.

Occurrence: Zinc sulfide occurs naturally as the mineral zinc blende, additionally called sphalerite, which is a mixture that iron and zinc sulfides.

Preparation: Zinc sulfide is typically prepared with several straightforward reactions, such as the combustion of a mixture of zinc and also sulfur, reacting zinc sulfate (ZnSO 4) through sodium sulfide (Na2S), or by passing hydrogen sulfide (H2S) gas into aqueous systems of any kind of Zn2+ salt to precipitate the insoluble ZnS. It is also prepared by reaction zinc oxide v hydrogen sulfide:

ZnO + H2S → ZnS + H2O

Physical properties: Zinc sulfide is uncovered in two various crystal forms, as pointed out above. The wurtzite type exists as white or yellowish-white crystals, while the sphalerite form exists together greyish white crystals. It has a density of 4.09 g/mL, and melting suggest of 1,185 °C.

Chemical properties: Zinc sulfide is completely insoluble in water. That decomposes in the presence of acids and strong oxidizing agents. In ~ temperatures greater than 900 °C, it decomposes with the release of zinc and also sulfur fumes, and also it likewise reacts with solid acids to relax hydrogen sulfide gas. As soon as heated come a temperature of 102 °C, the secure beta crystalline form of ZnS (sphalerite) changes into the alpha form (wurtzite). ZnS is a luminescent material, and exhibits phosphorescence as soon as illuminated with UV light.

Uses: Zinc sulfide has several applications as result of its luminescent property. That is doped with various activators and also used because that making phosphorescent and also electroluminescent materials. Zinc sulfide is supplied as a pigment, infrared optical material, and for make optical windows and also lenses. It is also a wide-bandgap semiconductor and also an efficient photocatalyst.

See more: Proof That The Product Of Two Rational Numbers Is Rational S Irrationals

Health effects/safety hazards: Zinc sulfide is not an extremely hazardous for humans and mainly causes irritation of skin, eyes and also respiratory tract upon exposure. However, that is taken into consideration a serious environmental hazard as it is extremely toxic come aquatic organisms.


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